Why droppings etch a finish at all
Fresh bird droppings run acidic, typically in the pH 3 to 4.5 range, and they contain insoluble residues that don't rinse cleanly away in a light shower. On a horizontal surface — a car hood, a windowsill, a gutter — droppings pool rather than run off, giving the acid time to sit. Direct sun and daily heating and cooling then bake that residue into the surface, which is why a splatter left on a car for a hot summer week routinely leaves a permanent ring even after it's finally washed off. This part of the story is well established and not in serious scientific dispute.

